The total deviation å of a light ray refracted through a prism can be calculated, given the incidence angle á. The same calculation allows for determination of the emergence angle ä.

Deviation Diagram for a
Prism

We have:

å=æ+ç

A=â+ã

=>A+å=(æ+â)+(ã+ç)

=>A+å=á+ä

=>å=á+ä-A (1)

sin(ä)/sin(â)=n=>ä=arcsin{n*sin(â)}

â=A-ã

=>ä=arcsin{n*sin(A-ã)} (2)

â=arcsin{sin(á)/n}, because
sin(á)/sin(â)=n again,

so (2)=>ä=arcsin{n*sin[A-arcsin(sin(á)/n)]} (3)

Now sin[A-arcsin(sin(á)/n)]=sin(A)*cos(arcsin(sin(á)/n))-cos(A)*sin(á)/n

So ä=arcsin{n*sin(A)*cos(arcsin(sin(á)/n))-cos(A)*sin(á)}

=arcsin{n*sin(A)*sqrt[1-(sin(á)/n)^{2}]-cos(A)*sin(á)}

=>ä=arcsin{sin(A)*sqrt[n^{2}-sin^{2}(á)]-cos(A)*sin(á)}
(4)

And finally:

(1)(4)=>

(5)

(5)
gives the deviation angle å, as a function of á, n_{ë} and A.

Here's a graph of the above equation, with A=60°, n_{D}=1.72803 (SF10
Crystal) and á ranging from 45° to 80°. Angles are measured in degrees on
the graph. Note that the deviation has a minimum, close to 60°. This fact can
also be experimentally demonstrated using the angle readers of a spectroscope or
numerically simulated (as in reference [2]).

Deviation Angle å as a
Function of Incidence Angle á

The above calculation
gives the deviation for an arbitrary angle á. When the incidence angle and the
emergence angle are the same, the prism is said to be in the position of
*minimum deviation*, for a given wavelength. Because light gets dispersed
into many wavelengths, this position can occur for a particular wavelength only.
Below are the calculations that lead to the fundamental formula for prisms in
the position of minimum deviation:

Minimum Deviation Diagram
for a Prism

For the position of minimum deviation, the ray travels perpendicular to the
bisect of angle A, and incidence and emergence angles are equal. Then:

á=ä
and â=ã (6)

Also: A=â+ã, å_{min}=(á-â)+(ä-ã) (7)

(7)(6)=>A=2*â, å_{min}=2*á-2*â or

â=A/2 and
å_{min}/2=á-A/2 => á=å_{min}/2+A/2 (8)

Now we know that
n=sin(á)/sin(â) so from the last equation and (8) we get:

(9)

For n_{D}=1.72803 and A=60°, expression (9) gives
å_{min}=59.54084145°, which is exactly the minimum displayed on the
graph above.

The actual *proof* that the angle å_{min} given by (9) __is__
in fact __the__ minimum of (5) is very complicated (it can be found in [3],
page 81). It can be proved using calculus, that if á is a root of the equation:
då/dá=0, with å given by (5), then
å(A,n,á)=2*arcin(n*sin(A/2))-A=å_{min}. A proof using Maple 9 commands,
is provided courtesy of Robert Israel. After you execute the commands, try to
understand *why* this is a perfectly valid proof.

>
epsilon:=(A,n,alpha)->alpha+arcsin(sin(A)*sqrt(n^2-sin(alpha)^2)-cos(A)*
sin(alpha))-A;

> S:= solve(diff(epsilon(A,n,alpha),alpha),alpha);

> S5:= simplify(S[5]) assuming n > 1, A > 0, A < Pi/2;#solutions
are not ordered in Maple. May need to change S[5]->some other S[n] here.

> Q:=sqrt((1-cos(epsilon(A,n,S5)+A))/2) - n*sqrt((1-cos(A))/2);

>
Q:= simplify(expand(Q)) assuming n>1,A > 0,A < Pi/2;

>
simplify(combine(Q)) assuming A > 0,A < Pi/2,n > 1;

Because the light dispersion angle is very small, (on the order of 7°) practically all the rays suffer minimum deviation. When a prism spectroscope is designed, its prism is placed in that position for usually the yellow part of the spectrum (sodium D lines). The Phasmatron spectroscope's prisms are placed in minimum deviation position for the green line of ë=5615.97363281A, its resonating wavelength.

__References__

- K.D. Alexopoulos, General
Physics: Optics, 1st Edition, Athens 1966 (in Greek).
- M.A. Peterson's Simulation Displaying the Minimum Deviation for a Prism
- C.J. Smith, A Degree
Physics Part III: Optics, Indian Edition 1985, Radha Publishing House.